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(±)-7-[[[(2-benzimidazolyl)methyl]amino]carbonyl]-4-methyl-3-oxo-2,3,4,5- tetrahydro- l H-l,4-benzodiazepine-2-acetic acid;2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-4-isopropyl-7-[[[(2-benzimidazolyl)methyl]amino]carbonyl]-3-oxo-2,3,4,5- tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-7-[[[N-(2-benzothiazolyl)methyl-N-methyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-7-[[[N-[2-(5(6)-chlorobenzimidazolyl)methyl]-N-methyl]amino] carbonyl]A- methyl-3-oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-indolyl)methyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5-tetrahydro-l H- l,4-benzodiazepine-2-acetic acid; (2S)-7-[[[(2-Benzimidazolyl)methyl]amino]carbonyl]-4-methyl-3-oxo-2,3,4,5- tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; (2R)-7-[[[(2-Benzimidazolyl)methyl]amino]carbonyl]-4-methyl-3-oxo-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-benzimidazolyl)methyl]amino]carbonyl]-9-chloro A-methyl-3-oxo-2,3,4,5-tetrahydro- l H-2-benzazepine-4-acetic acid; (±)-7-[[[N-(2-benzimidazolyl)medιyl-N-methyl]amino]carbonyl]-3-oxo A-(2- phenylethyl)-2,3,4,5-tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[N-(2-benzimidazolyl)methyl-N-methyl]amino]methyl]- 1 ,4-dimethyl-3-oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)A-Methyl-7-[[[N-(2-(l-methyl)benzimidazolyl)methyl-N-methyl]amino] carbonyl]-3-oxo-2,3,4,5-tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-(5(6)-methoxy)benzimidazolyl)methyl]amino]carbonyl]A-methyl-3-oxo-2,3 ,4,5-tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[N-[2-(4-azabenzimidazolyl)]medιyl-N-methyl]amino]carbonyl]A-methyl-3- oxo-2,3 ,4,5-tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[N-[2-(5(6)-Azabenzimidazolyl)]methyl-N-methyl]amino] carbonyl]-4- methyl-3-oxo-2,3 ,4,5-tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-imidazolyl)methyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5-tetrahydro-1 H- 1 ,4-benzodiazepine-2-acetate; (±)-7-[[[2-(benzimidazolyl)methyl]methylamino]carbonyl]A-(2-methoxyethyl)-3- oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-7-[[[2-(4-Azabenzimidazolyl)methyl]methylamino]carbonyl]A-(2- methoxyethyl)-3-oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-7-[[[2-(l-methylindolyl)methyl]methylamino]carbonyl]A-methyl-3-oxo-2,3,4,5- tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[2-(l-methylindolyl)methyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; [[[(2RS-indolinyl)methyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5-tetrahydro-l H- l,4-benzodiazepine-2S-acetic acid;(±)-7-[[[(2-imidazolyl)medιyl]amino]carbonyl]-3-oxo A-(2-phenylethyl)-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-benzimidazolyl)methyl]amino]medιyl]A-methyl-3-oxo-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-benzimidazolyl)methyl]amino]carbonyl]- 1 ,4-dimethyl-3-oxo-2,3 ,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[(2-benzimidazolyl)methyl]methylamino]carbonyl]-3-oxo-2,3,4,5- tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (2S)-7-[[[N-butyl-N-benzimidazol-2-yl)methyl]amino]carbonyl]-3-oxo A-methyl- 2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid;7-[[[N-(2-benzimidazolyl)methyl-N-(2-phenylethyl)]amino]carbonyl]A-methyl-3- oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; 7-[[[N-(2-benzimidazolyl)methyl-N-carboxymethyl]amino]carbonyl]-4-methyl-3- oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; 7-[[[N-(2-benzimidazolyl)methyl-N-cyclohexyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5-tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; 7-[[[2-(5,6-methylendioxybenzimidazolyl)methyl]methylamino] carbonyl]-4- methyl-3-oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; 7-[[[2-(4,6-diazabenzimidazolyl)methyl]methylamino]carbonyl]A-methyl-3-oxo- 2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid;7-[[[2-(5,6-dimethoxybenzimidazolyl)methyl]methylamino]carbonyl]A-methyl-3- oxo-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-8-[[2-(2-benzimidazolyl)acetyl]amino]-2-methyl-3-oxo-2,3,4,5-tetrahydro-l H-2- benzazepine A-acetic acid; (±)-8-[[[(2-benzimidazolyl)methyl]medιylamino]carbonyl]A-memyl-3-oxo-2,3,4,5- tetrahydro- 1 H-2-benzazepine A-acetic acid; 7-[[[(2-benzimidazolyl)methyl]methylamino]carbonyl]-3-oxo-4-(2-phenylethyl)-2,3,4,5-tetrahydro-l H-l,4-benzodiazepine-2-acetic acid; (±)-7-[[[2-(benzimidazolyl)methyl]amino]carbonyl-4-[2-(3,4- methylenedioxyphenyl)ethyl]-3-oxo-2,3,4,5-tetrahydro-l H-l,4- benzodiazepine-2-acetic acid; (±)--[[[(4(5)-imidazolyl)methyl]amino]carbonyl]-4-methyl-3-oxo-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-[[[4-(2-phenylimidazolyl)methyl]amino]carbonyl]-4-methyl-3-oxo-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; (±)-7-[[[2-(3-indolyl)ethyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5-tetrahydro-l H- l,4-benzodiazepine-2-acetic acid; 7-[[[2-(4-phenylimidazolyl)methyl]amino]carbonyl]A-methyl-3-oxo-2,3,4,5- tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid; ( /-)-2,3,4,5-Tetrahydro-7-[[[benzimidazol-2-yl)methyl]methylamino]carbonyl]-4- (3,3-dimethylbutyl)-3-oxo- 1 H- 1 ,4-benzodiazepine-2-acetic acid;2,3,4,5-tetrahydro A-methyl-3-oxo-benzodiazepine-2-acetic acid; (-)-7-[[[4,7-Dimethoxybenzimidazoyl-2-ylmethyl]aminomethyl]carbonyl]-2,3,4,5- tetrahydro-4-methyl-3-oxo-benzodiazepine-2-acetic acid; ( /-)-2,3,4,5-Tetrahydro-7-[[[(benzimidazol-2-yl)methylamino]carbonyl]-4-(3,3- dimetiιylbutyl)-3-oxo-l H-l,4-benzodiazepine-2-acetic acid; (-)-7-[[[7-Methylbenzimidazol-2-ylmethyl]methylamino]carbonyl]-2,3,4,5- tetrahydro A-methyl-3-oxo- 1 ,4-benzodiazepine-2-acetic acid; (2S)-[[[N-aminobutyl-N-(benzimidazlo-2-yl)methyl]amino]carbonyl]-3-oxo-4- methyl-2,3 ,4,5-tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acidbis(trifluoroacetate)salt; (2S)-[[[N-cyanomethyl-N-(benzimidazlo-2-yl)methyl]amino]carbonyl]-3-oxo-4- methyl-2,3 ,4,5-tetrahydro- IH- 1 ,4-benzodiazepine-2-acetic acid dihydrochloride salt; 2,3,4,5-Tetrahydro-7-[[[(benzimidazol-2-yl)]methyl]amino]carbonyl]A-(4- phthalimidobutyl)-3-oxo- 1 ,4-benzodiazepine-2-acetic acid; (-)-7-[[[Imidazo[4,5B]A,6-dimethylpyridyl-2-ylmethyl]aminomethyl]carbonyl]-2,3,4,5-tetrahydro A-methyl-3-oxo-benzodiazepine-2-acetic acid trifluoroacetate salt; ( /-)-7-[[(2-Benzimidazol-2-ylmethyl)-N-methylamino]carbonyl]-2,3,4,5- tetrahydro-3-oxo A-[2-(3',4'-methylenedioxyphenyl)ethyl]- 1 H- 1 ,4- benzodiazepine-2-acetic acid; ( /-)-2,3,4,5-Tetrahydro-7-[[[(Benzimidazol-2-yl)methyl]amino]carbonyl]A-(2- methoxyethyl)-3-oxo-l H-l,4-benzodiazepine-2-acetic acid;7-[[2-[l-Methylbenzimidazolyl]benzimidazolylmethylamino]carbonyl]-2,3,4,5- tetrahydro A-methyl-3-oxo- 1 H- 1 ,4-benzodiazepine-2-acetic acid; 7-[[[N-Cyclohexyl-N-(benzimidazol-2-yl)methyl]amino]carbonyl]-3-oxo-2,3,4,5- tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; 7-[[[2-Bis-(Benzimidazolylmethyl)aminocarbonyl]-2,3,4,5-tetrahydro-4-methyl-3- oxo- 1 H- 1 ,4-benzodiazepine-2-acetic acid; ( /-)-2,3,4,5-Tetrahydro-7-[[[imidazo[4,5-B]pyrid-2- yl]methyl]methylamino]carbonyl]A-(3,3-dimethylbutyl)-3-oxo-l H-l,4- benzodiazepine-2-acetic acid; ( /-)-7-[[(2-Benzimidazol-2-ylmethyl)-N-methylamino]carbonyl-2,3,4,5-tetrahydro-3-oxo A-(2',2',2'-trifluoroethyl)- 1 H- 1 ,4-benzodaizepine-2-acetic acid; ( /-)-7-[[(2-Benzimidazolyl)acetyl]amino]-5-oxo A-(2-phenyledιyl)-2,3,4,5- tetrahydro- 1 H- 1 ,4-benzodiazepine-2-acetic acid; ( /-)-7-[[(2-Benzimidazol-2-ylmethyl)amino]carbonyl]-2,3,4,5-tetrahydro-3-oxo-4- (2',2',2'-trifluoroethyl)- 1 H- 1 ,4-benzodiazepine-2-acetic acid;(-)-7-[[[5,6-Difluorobenzimidazoyl-2-ylmethyl]aminomethyl]carbonyl]-2,3,4,5- tetrahydro A-methyl-3-oxo-l,4-benzodiazepine-2-acetic acid; and ( /-)-7-[[Bis-(Benzimidazol-2-ylmethyl)amino]carbonyl]-2,3,4,5-tetrahydro A- phenylethyl-3-oxo- 1 H- 1 ,4-benzodiazepine-2-acetic acidtris(trifluoroacetate)salt.(±)A-[[2-[(Benzimidazol-2-yl)methyl]methylamino]-l-hydroxyethyl]-l,2-phenylene dioxydiacetic acid; 4-[2-[[(Benzimidazol-2-yl)methyl]methylamino]acetyl]-l,2-phenylenedioxydiacetic acid; or 3-[[4-[[[(Benzimidazol-2-yl)methy]amino]carbonyl]phenyl]amino]propionic acid.33. Concentration under vacuum left a residue which was diluted with water and allowed to stand at RT overnight.


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